Watch the clock

During the third hour after midnight the hands on a clock point in the same direction (so one hand is over the top of the other). At what time, to the nearest second, does this happen?
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Problem

 

During the third hour after midnight the hands on a clock pointed in the same direction (so one hand was over the top of the other).

At what time, to the nearest second, did this happen?

 

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Watch the clock