Hamilton's Puzzle

I start my journey in Rio de Janeiro and visit all the cities as Hamilton described, passing through Canberra before Madrid, and then returning to Rio. What route could I have taken?
Exploring and noticing Working systematically Conjecturing and generalising Visualising and representing Reasoning, convincing and proving
Being curious Being resourceful Being resilient Being collaborative

Problem

In 1859, the Irish mathematician Sir William Rowan Hamilton devised a puzzle with a regular dodecahedron made of wood. Here is a dodecahedron:

He labelled each of the vertices with the name of an important city. The challenge was to find a route along the edges of the dodecahedron which visited every city exactly once and returned to the start.

Here is a graph which represents the dodecahedron. Can you see how each of the 20 vertices, 30 edges and 12 pentagonal faces is represented in the graph?

I start my journey in Rio de Janeiro and visit all the cities as Hamilton described, passing through Canberra before Madrid, and then returning to Rio. What route could I have taken?

Can you find any other ways of making this journey?

Here is a simpler network of countries:

How many different ways are there of visiting each of these countries once and only once, beginning and ending at Australia?