Let the first two terms of the sequence be $a$ and $b$ respectively.
Then the next three terms are $a+b$, $a+2b$, $2a+3b$. So $2a+3b = 2004$.
For $a$ to be as large as possible, we need $b$ to be as small as possible, consistent with both being positive integers.
If $b=1$ then $2a=2001$, but $a$ is an integer, so $b\not=1$.
However, if $b=2$ then $2a=1998$, so the maximum possible value of $a$ is $999$, giving us the first five terms:
$999$, $2$, $1001$, $1003$, $2004$