Why do this problem?
This
problem
gives an interesting problem solving challenge for students aged
16/17 with an interest in both chemistry and mathematics. It gives
a good exercise in mathematical modelling: a physical process needs
to be represented by equations which may then be analysed
mathematically. It is not simply routine, nor is it especially
difficult if considered in the right ways. However, it is a good
example of a situation in which simply trying to 'do the algebra'
will not work.
Possible approach
This problem works well for individual use. It could be solved
numerically, using trial and error, or graphically using many ideas
from linear algebra.
If done as a group or set as a homework, it would be
interesting to compare solutions, as there as several different
possible routes to a conclusion. What do students think of each
others answers? Which seem most powerful? Neatest?
Key questions
Could the sample be a pure sample of a single isotope?
Why?
How many pieces of information are given to us in the
question?
Is there any way of distinguishing between the different
isotopes for the timescales given?
Chemically, what is happening in the decay? How does decay
affect the mass of the sample? Is this a significant effect?
Possible extension
Chemical extension:
- Consider carefully the effects of the decay on the mass of the
sample, taking into account that some matter will be
lost.
- Energy is radiated from the system during decay. Energy is
related to mass via Einstein's equation $E=mc^2$. Is this effect
relevant or significant?
Mathematical Extension:
- Explore how many more data points would be needed to give a
unique solution to the problem. What is the minimum number of extra
data points needed to give a unique solution?
Possible support
Encourage trial and error, starting with equal masses of each
sample. Then raise or lower the proportions of two of the masses,
using a spreadsheet to do the numerical calculations.