This solution came from Ruth from
Manchester High School for Girls. Well done Ruth!
Let the tetrahedron's vertices be $A$, $B$, $C$ and $D$ and the
longest side be $AB$. If you assume that there is not a vertex
where the three sides meeting at it could be the sides of a
triangle, we must have $AC + AD < AB$ and $BC + BD < AB$
(otherwise the sides meeting at $A$ or $B$ could be the sides of a
triangle). Therefore
$$AC + AD + BC + BD< 2 AB$$.Now since $ABC$ and
$ABD$ are both triangles, we must have $AC + BC > AB$ and $AD +
BD > AB$. Therefore
$$AC+ AD + BC + BD > 2 AB$$. This contradicts (1),
so the initial assumption must be wrong. There is at least one
vertex (one of $A$ or $B$) where the three sides meeting at it
could be the sides of a triangle.