London has coordinates (0.622515,0,0.782608) taking the earth as unit radius.
Sydney has coordinates (-0.72509,0.401925,-0.55919).

The straight line 'tunnel' distance between the two cities is
2d=1.943713


sinθ= d R =0.97186

Hence
θ=1.33300radians=76. 38o .

The angle between the radii to the 2 places is 2.666 radians so, taking the radius of the earth to be 6378 kilometres, the distance between London and Sydney is 17,000 kilometres to the accuracy of this calculation.

This distance is RΘ where Θ is the angle between the radii to the 2 places. At an altitude of 6 kilometres the distance is (R+6)Θ and the 'extra' distance is 6Θ=16 kilometres.