Why do people say that water is necessary for life? Why have we
never found any living organism that can flourish in a completely
dry environment? How is it that something odourless, colourless,
tasteless and relatively unreactive makes up 60% of our body mass?
Why could another liquid not be used? Why water?
Water has several properties that make it unique amongst
compounds and make it possible for all forms of known life to
function.
It is the only natural substance
found in all three physical states at the temperatures that
naturally occur on Earth.
This means that we see water as a liquid, in rivers and seas, a
solid, as snow and ice, and as a gas, as clouds or steam. If this
was not the case the water cycle would be completely different
(what if water didn't evaporate in the sun?); snow and ice might
not exist (and thousands of species would now be homeless) and
weather would be very different (would it still rain?). Can you
think of anything else that would be different? Do you think we
could still live if water was only a liquid at the temperatures
that occur naturally on Earth? What about only a gas/solid?
Ice is less dense than
water
This just means that ice floats on water and that lakes freeze from
the top down to the bottom. This is clearly important for animals
that live on ice, as their habitats would be greatly reduced or not
exist at all if ice sank. Similarly, fish and other pond-life would
be affected if lakes and ponds froze from the bottom upwards - the
layer of frozen water at the top of the pond provides some
insulation and prevents the rest of the water getting cold as
quickly. It does this by making a barrier between the cold air and
the water below. This means that large bodies of water don't get
cold deeper down as fast as they might if ice sank and helps
wildlife survive in ponds over winter. In fact, water gets more
dense at it is cooled until it reaches $4^\circ$ C (which you can
see on the graph), after which it gets less dense again. Most
substances get progressively more dense as they are cooled. The
graph below shows how density of water changes with
temperature.
Water has a very high melting and
boiling point compared to other similar molecules
This is what means it is seen as a solid, a liquid and a gas on
Earth. If water was not a liquid at most of the temperatures we see
on Earth the seas would all be ice, there would be no rain, nothing
for plants to collect and animals to drink. Even our cells are
filled with liquid water, which would not be possible either.
It is called the 'universal
solvent' because it is capable of dissolving so many
substances.
The water in our bodies is mostly contained in our cells, where it
gives them a clear shape as well as having billions of useful
molecules dissolved in it. Our cells need to be filled with water
to work properly because the enzymes inside them only work in
solution. Water is also the means by which transport occurs in our
bodies' blood is mostly water and has hormones and gasses
dissolved in it as well as toxins such as urea, which are removed
from the body with yet more water. Transport in water also occurs
on a much smaller scale: when something is dissolved it can move
around in the solvent. For example, if an enzyme needs calcium ions
to be activated and start working it will meet these as they move
about in the solution inside a cell. The higher the concentration
of calcium in the cell, the more likely the enzyme will meet an ion
sooner. You may also have learnt about diffusion and osmosis, which
are key concepts in understanding how cells function and rely on
the presence of water
Water has a high specific
heat capacity.
While this idea sounds a bit intimidating it is actually very
simple - all it means is that it takes a lot of energy to make
water a little bit warmer. This is why on a hot day the sand on a
beach can be too hot to walk on but the sea still feels cool; the
energy from the sun is enough to heat the sand a lot but the water
only a little. This has some very important implications,
especially for organisms that live in water. Seas, lakes and rivers
maintain a much more constant temperature than air, which means
that animals can live in water all year round without having to
adapt to large temperature changes (What do you think would happen
if water cooled more easily? What problems might this pose to
organisms living in a small pond?). This also means that our body
temperature is reasonably difficult to change quickly and hence
makes our brain's job of maintaining a constant body temperature
much easier (What might happen if our body temperature changed
quickly and easily?).
Surface tension
You might have noticed that if you put a needle on the surface of a
bowl of water it floats but if you throw it in it sinks. This is
because the needle is denser than water so wants to sink but is
held up by the surface tension of the water. Surface tension is a
property that means the surface of water does not want to break
- it is 'sticky'. You can also see this when you fill a cup to
the brim, as the surface of the water will hold together and resist
spilling. The high surface tension of water is the reason that some
flies can land on its surface without sinking. This concept is also
very closely related to another, the idea of capillary
action.
Capillary
action
Similarly to surface tension, this revolves around the idea that
molecules of water 'stick' together. If you put a very fine tube
into a beaker of water you will see that some of the water travels
a short way up the tube; this is called capillary action and is
caused by the water clinging to the sides of the tube and to other
molecules of water, pulling them up the tube with it. Eventually
the weight of the water being pulled is too great to be supported
and the water stops moving, having reached an equilibrium. This
same principle allows plants to draw water up from the ground; as
water molecules travel up the stem more water molecules stick to
them and more stick to those and so on until a column of water is
being transported in the xylem (to find out more about this, look
up 'transpiration').
But why?
All of these properties of water are critical for life as we know
it but why does water have them? Does no other substance also do
these things? What is it about water that makes it different? To
understand the answers to these questions you have to study the
molecular structure of water. The chemical formula for water is
H2O, meaning that it contains two hydrogen atoms covalently bonded
to one oxygen atom, like this:
The 95.84pm shows the length of the bond between the oxygen and the
hydrogen; one pm is short for a picometre, which is one trillionth
of a metre. The angle shown is the acute angle between the two
hydrogen nuclei (do you have any ideas about why it isn't
$180^\circ$ ? Why should it be $180^\circ$ ?) This diagram
represents the bonds as lines, which makes it look like they are
the same at every point ? this is not the case. Because oxygen is
more electronegative than hydrogen it attracts the electrons in the
O-H bond towards itself. If the thickness of the line represents
electron density (the amount of time electrons spend in that part
of the bond), the O-H bond actually looks more like this:
PICTURE showing polarisation of bond
As you can see the electrons spend most of their time nearer to the
oxygen nucleus. This means that the oxygen is slightly negatively
charged and that the hydrogens are slightly positively charged.
This is called polarity and is the key concept behind the
properties of water
PICTURE TO BE RE SIZED -
This means that weak ionic interactions can occur between
neighbouring water molecules as the slightly positive hydrogen from
one molecule is attracted to the slightly negative oxygen on
another. These are called hydrogen bonds.
This is why water 'sticks' to itself, giving it high surface
tension and the ability to move by capillary action.
A great deal of energy is required to break down the hydrogen
bonds, which is why the melting and boiling points of water are
high and why it has a high specific heat capacity
A substance will dissolve in water if it is polar or ionic. This
is because it dissolves by forming hydrogen bonds with the water.
Oil is not polar, which is why it will not dissolve. Salt, NaCl,
does dissolve because it is ionic. Can you think of some other
substances that are soluble in water? How do they form hydrogen
bonds with it? Can you draw a similar picture to the one below
showing why glucose is soluble? Is it more or less soluble in water
than salt? Why do you think this is?
A diagram of what happens to NaCl in solution:
This is an image of the chemical structure of glucose. There
is a C (carbon atom) at each vertex - this is a common way of
drawing organic molecules.